Selenium () is a
chemical element with
atomic number 34, with the chemical symbol
Se. It is a
nonmetal, chemically related to
sulfur and
tellurium, and rarely occurring in its elemental state in nature. It is toxic in large amounts, but trace amounts of it are necessary for cellular function in most, if not all, animals, forming the active center of the enzymes
glutathione peroxidase and
thioredoxin reductase (which indirectly reduce certain oxidized molecules in animals and some plants) and three known
deiodinase enzymes (which convert one
thyroid hormone to another). Selenium requirements in plants differ by species, with some plants apparently requiring none.
Isolated selenium occurs in several different forms, the most stable of which is a dense purplish-gray semi-metal (semiconductor) form that is structurally a trigonal polymer chain. It conducts
electricity better in the light than in the dark, and is used in
photocells (see allotropic section below). Selenium also exists in many non-conductive forms: a black glass-like allotrope, as well as several red crystalline forms built of eight-membered
ring molecules, like its lighter chemical cousin sulfur.
Selenium is found in economic quantities in
sulfide ores such as
pyrite, partially replacing the
sulfur in the ore matrix. Minerals that are selenide or selenate compounds are also known, but all are rare.
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