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Search term: SNHMUERNLJLMHN-UHFFFAOYAQ
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Inherent Properties, Identifiers and References
ChemSpider ID: 11087
Empirical Formula: C6H5I
Molecular Weight: 204.0084
Nominal Mass: 204 Da
Average Mass: 204.0084 Da
Monoisotopic Mass: 203.943585 Da
Systematic Name: iodobenzene
SMILES: Ic1ccccc1
InChI: InChI=1/C6H5I/c7-6-4-2-1-3-5-6/h1-5H
InChIKey: SNHMUERNLJLMHN-UHFFFAOYAQ
Std. InChI: InChI=1S/C6H5I/c7-6-4-2-1-3-5-6/h1-5H
Std. InChIKey: SNHMUERNLJLMHN-UHFFFAOYSA-N
(Details...) Wikipedia Article(s)
Iodobenzene is an organic compound consisting of a benzene ring substitituted with one iodine atom. It is useful as a synthetic intermediate in organic chemistry. Since the C-I bond is weaker than C-Br or C-Cl, it is more reactive than bromobenzene or chlorobenzene. Iodobenzene can react with magnesium to form a Grignard reagent, phenylmagnesium iodide. Phenylmagnesium iodide, like the bromide analog, is a synthetic equivalent for the phenyl anion synthon. It can also serve as a substrate for the Sonogashira coupling, Heck reaction, and other metal-catalyzed couplings. Read more... or Edit at Wikipedia...
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User Data

  • experimental physchem properties
    • Melting Point: -29
    • Boiling Point: 63-65/10mm
    • Flash Point: 74(165F)
    • Specific Gravity: 1.826
    • Refraction Index: 1.6200
  • miscellaneous
    • Safety: WARNING: Irritates eyes, lungs, may be harmful if swallowed
Names and Synonyms

Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Redirected by Users, Redirect Approved by Experts

benzene, ​iodo-

iodo-benz​ene

Iodobenze​ne [Wiki]

phenyliod​onium

172484-65​-0 [RN]

209-719-6 [EINECS/ELINCS]

591-50-4 [RN]

Iodineben​zol

MFCD00001​029

Phenyl io​dide

Database ID(s)

Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Redirected by Users, Redirect Approved by Experts

ACD/LogP: 3.25 # of Rule of 5 Violations: 0
ACD/LogD (pH 5.5): 3.25 ACD/LogD (pH 7.4): 3.25
ACD/BCF (pH 5.5): 173.78 ACD/BCF (pH 7.4): 173.78
ACD/KOC (pH 5.5): 1396.37 ACD/KOC (pH 7.4): 1396.37
#H bond acceptors: 0 #H bond donors: 0
#Freely Rotating Bonds: 0 Polar Surface Area: 0 Å2
Index of Refraction: 1.619 Molar Refractivity: 39.15 cm3
Molar Volume: 111.5 cm3 Polarizability: 15.52 10-24cm3
Surface Tension: 41.4 dyne/cm Density: 1.829 g/cm3
Flash Point: 74.4 °C Enthalpy of Vaporization: 40.72 kJ/mol
Boiling Point: 188.3 °C at 760 mmHg Vapour Pressure: 0.831 mmHg at 25°C
            
 Log Octanol-Water Partition Coef (SRC):
    Log Kow (KOWWIN v1.67 estimate) =  3.16
    Log Kow (Exper. database match) =  3.25
       Exper. Ref:  Hansch,C et al. (1995)

 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42):
    Boiling Pt (deg C):  195.18  (Adapted Stein & Brown method)
    Melting Pt (deg C):  -15.50  (Mean or Weighted MP)
    VP(mm Hg,25 deg C):  0.641  (Mean VP of Antoine & Grain methods)
    MP  (exp database):  -31.3 deg C
    BP  (exp database):  188.4 deg C
    VP  (exp database):  1.06E+00 mm Hg at 25 deg C

 Water Solubility Estimate from Log Kow (WSKOW v1.41):
    Water Solubility at 25 deg C (mg/L):  69.98
       log Kow used: 3.25 (expkow database)
       no-melting pt equation used
     Water Sol (Exper. database match) =  340 mg/L (30 deg C)
        Exper. Ref:  CHIOU,CT ET AL. (1977)

 Water Sol Estimate from Fragments:
    Wat Sol (v1.01 est) =  85.649 mg/L
    Wat Sol (Exper. database match) =  340.00
       Exper. Ref:  CHIOU,CT ET AL. (1977)

 ECOSAR Class Program (ECOSAR v0.99h):
    Class(es) found:
       Neutral Organics

 Henrys Law Constant (25 deg C) [HENRYWIN v3.10]:
   Bond Method :   1.25E-003  atm-m3/mole
   Group Method:   1.69E-003  atm-m3/mole
   Exper Database: 1.25E-03  atm-m3/mole
 Henrys LC [VP/WSol estimate using EPI values]:  2.459E-003 atm-m3/mole

 Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:
  Log Kow used:  3.25  (exp database)
  Log Kaw used:  -1.292  (exp database)
      Log Koa (KOAWIN v1.10 estimate):  4.542
      Log Koa (experimental database):  None

 Probability of Rapid Biodegradation (BIOWIN v4.10):
   Biowin1 (Linear Model)         :   0.0199
   Biowin2 (Non-Linear Model)     :   0.0003
 Expert Survey Biodegradation Results:
   Biowin3 (Ultimate Survey Model):   2.7254  (weeks-months)
   Biowin4 (Primary Survey Model) :   3.4312  (days-weeks  )
 MITI Biodegradation Probability:
   Biowin5 (MITI Linear Model)    :  -0.2377
   Biowin6 (MITI Non-Linear Model):   0.0000
 Anaerobic Biodegradation Probability:
   Biowin7 (Anaerobic Linear Model):  0.5771
 Ready Biodegradability Prediction:   NO

Hydrocarbon Biodegradation (BioHCwin v1.01):
    Structure incompatible with current estimation method!

 Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:
  Vapor pressure (liquid/subcooled):  141 Pa (1.06 mm Hg)
  Log Koa (Koawin est  ): 4.542
   Kp (particle/gas partition coef. (m3/ug)):
       Mackay model           :  2.12E-008 
       Octanol/air (Koa) model:  8.55E-009 
   Fraction sorbed to airborne particulates (phi):
       Junge-Pankow model     :  7.67E-007 
       Mackay model           :  1.7E-006 
       Octanol/air (Koa) model:  6.84E-007 

 Atmospheric Oxidation (25 deg C) [AopWin v1.92]:
   Hydroxyl Radicals Reaction:
      OVERALL OH Rate Constant =   1.2856 E-12 cm3/molecule-sec
      Half-Life =     8.320 Days (12-hr day; 1.5E6 OH/cm3)
      Half-Life =    99.839 Hrs
   Ozone Reaction:
      No Ozone Reaction Estimation
   Fraction sorbed to airborne particulates (phi): 1.23E-006 (Junge,Mackay)
    Note: the sorbed fraction may be resistant to atmospheric oxidation

 Soil Adsorption Coefficient (PCKOCWIN v1.66):
      Koc    :  268
      Log Koc:  2.428 

 Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v1.67]:
    Rate constants can NOT be estimated for this structure!

 Bioaccumulation Estimates from Log Kow (BCFWIN v2.17):
   Log BCF from regression-based method = 1.803 (BCF = 63.46)
       log Kow used: 3.25 (expkow database)

 Volatilization from Water:
    Henry LC:  0.00125 atm-m3/mole  (Henry experimental database)
    Half-Life from Model River:      2.127  hours
    Half-Life from Model Lake :        143  hours   (5.957 days)

 Removal In Wastewater Treatment:
    Total removal:              38.65  percent
    Total biodegradation:        0.11  percent
    Total sludge adsorption:     6.93  percent
    Total to Air:               31.62  percent
      (using 10000 hr Bio P,A,S)

 Level III Fugacity Model:
           Mass Amount    Half-Life    Emissions
            (percent)        (hr)       (kg/hr)
   Air       8.02            233          1000       
   Water     14.2            900          1000       
   Soil      77.2            1.8e+003     1000       
   Sediment  0.571           8.1e+003     0          
     Persistence Time: 629 hr