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2Asymmetric synthesis of unusual amino acids: Synthesis of Tyr and Phe analogs, Peptides Synthesis, characterization and thermal decomposition of new complexes of Emphasis Type=u201dItalicu201dp/Emphasis-methyl-, Emphasis Type=u201dItalicu201dp/Emphasis-trifluoromethyl- and Emphasis Type=u201dItalicu201dp/Emphasis-bromo-phenylalanine with copper, Journal of Thermal Analysis and Calorimetry