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3First example of borirane synthesis by ??-olefins reaction with BCl3??SMe2 Catalyzed with (??5-C5H5)2TiCl2, Russian Journal of Organic Chemistry Mechanism of catalytic cycloboration of ??-olefins with boron trichloride: the synthesis of hardly obtainable boriranes and the mechanistic DFT study of transmetalation of titanacyclopropane intermediates, Kinetics and Catalysis Synthesis of 1-fluoro-2-alkylboriranes by the reaction of ??-olefins with BF3??THF catalyzed by Cp2TiCl2, Russian Journal of General Chemistry