ChemSpider 2D Image | cannabigerolic acid | C22H32O4

cannabigerolic acid

  • Molecular FormulaC22H32O4
  • Average mass360.487 Da
  • Monoisotopic mass360.230072 Da
  • ChemSpider ID4952655

  • Double-bond stereo - Double-bond stereo

More details:

Validated by Experts, Validated by Users, Non-Validated, Removed by Users

25555-57-1 [RN]
3-[(2E)-3,7-Dimethyl-2,6-octadien-1-yl]-2,4-dihydroxy-6-pentylbenzoesäure [German] [ACD/IUPAC Name]
3-[(2E)-3,7-Dimethyl-2,6-octadien-1-yl]-2,4-dihydroxy-6-pentylbenzoic acid [ACD/IUPAC Name]
Acide 3-[(2E)-3,7-diméthyl-2,6-octadién-1-yl]-2,4-dihydroxy-6-pentylbenzoïque [French] [ACD/IUPAC Name]
Benzoic acid, 3-[(2E)-3,7-dimethyl-2,6-octadien-1-yl]-2,4-dihydroxy-6-pentyl- [ACD/Index Name]
cannabigerolic acid
(E)-3-(3,7-Dimethyl-2,6-octadienyl)-2,4-dihydroxy-6-pentylbenzoic acid
3-(3,7-dimethyl-2,6-octadienyl)-2,4-dihydroxy-6-pentylbenzenecarboxylic acid
3-[(2E)-3,7-dimethyl-2,6-octadien-1-yl]-2,4-dihydroxy-6-pentyl-benzoic acid
3-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-2,4-dihydroxy-6-pentylbenzoic acid
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Validated by Experts, Validated by Users, Non-Validated, Removed by Users

80I4ZM847Y [DBID]
UNII:80I4ZM847Y [DBID]
UNII-80I4ZM847Y [DBID]
  • Miscellaneous

    • Chemical Class:

      A dihydroxybenzoic acid that is olivetolic acid in which the hydrogen at position 3 is substituted by a geranyl group. A biosynthetic precursor to <greek>Delta</greek><smallsup>9</smallsup>-tetrahydro cannabinol, the principal psychoactive constituent of the cannabis plant. ChEBI CHEBI:67081
      A dihydroxybenzoic acid that is olivetolic acid in which the hydrogen at position 3 is substituted by a geranyl group. A biosynthetic precursor to Delta(9)-tetrahydrocannabinol, the principal psychoac tive constituent of the cannabis plant. ChEBI CHEBI:67081
      A dihydroxybenzoic acid that is olivetolic acid in which the hydrogen at position 3 is substituted by a geranyl group. A biosynthetic precursor to Delta9-tetrahydro; cannabinol, the principal psychoac tive constituent of the cannabis plant. ChEBI https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:67081

    • Compound Source:

      cannabinoid biosynthesis PlantCyc CPD-7166, CPD-7166, CPD-7166
      Cannabis sativa PlantCyc CPD-7166
      Humulus lupulus var. lupulus PlantCyc CPD-7166
      Linum usitatissimum PlantCyc CPD-7166

    • Bio Activity:

      cannabigerolate + oxygen -> cannabichromenate + hydrogen peroxide PlantCyc CPD-7166, CPD-7166, CPD-7166
      cannabigerolate + oxygen -> cannabidiolate + hydrogen peroxide PlantCyc CPD-7166, CPD-7166, CPD-7166
      cannabigerolate + oxygen -> Delta9-tetrahydrocannabinolate + hydrogen peroxide PlantCyc CPD-7166, CPD-7166, CPD-7166
      geranyl diphosphate + olivetolate -> cannabigerolate + diphosphate PlantCyc CPD-7166, CPD-7166
      olivetolate + geranyl diphosphate -> cannabigerolate + diphosphate PlantCyc CPD-7166

Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, version: 14.00

Density: 1.1±0.1 g/cm3
Boiling Point: 535.7±50.0 °C at 760 mmHg
Vapour Pressure: 0.0±1.5 mmHg at 25°C
Enthalpy of Vaporization: 85.5±3.0 kJ/mol
Flash Point: 291.9±26.6 °C
Index of Refraction: 1.555
Molar Refractivity: 106.8±0.3 cm3
#H bond acceptors: 4
#H bond donors: 3
#Freely Rotating Bonds: 10
#Rule of 5 Violations: 1
ACD/LogP: 8.31
ACD/LogD (pH 5.5): 4.73
ACD/BCF (pH 5.5): 489.18
ACD/KOC (pH 5.5): 468.25
ACD/LogD (pH 7.4): 4.38
ACD/BCF (pH 7.4): 219.57
ACD/KOC (pH 7.4): 210.18
Polar Surface Area: 78 Å2
Polarizability: 42.3±0.5 10-24cm3
Surface Tension: 43.9±3.0 dyne/cm
Molar Volume: 332.9±3.0 cm3

Predicted data is generated using the US Environmental Protection Agency�s EPISuite™ 

                        
 Log Octanol-Water Partition Coef (SRC):
    Log Kow (KOWWIN v1.67 estimate) =  8.17

 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42):
    Boiling Pt (deg C):  513.47  (Adapted Stein & Brown method)
    Melting Pt (deg C):  218.89  (Mean or Weighted MP)
    VP(mm Hg,25 deg C):  1.98E-012  (Modified Grain method)
    Subcooled liquid VP: 2.33E-010 mm Hg (25 deg C, Mod-Grain method)

 Water Solubility Estimate from Log Kow (WSKOW v1.41):
    Water Solubility at 25 deg C (mg/L):  0.002152
       log Kow used: 8.17 (estimated)
       no-melting pt equation used

 Water Sol Estimate from Fragments:
    Wat Sol (v1.01 est) =  0.00068402 mg/L

 ECOSAR Class Program (ECOSAR v0.99h):
    Class(es) found:
       Phenols-acid
       Salicylic Acid-acid

 Henrys Law Constant (25 deg C) [HENRYWIN v3.10]:
   Bond Method :   7.72E-011  atm-m3/mole
   Group Method:   Incomplete
 Henrys LC [VP/WSol estimate using EPI values]:  4.364E-010 atm-m3/mole

 Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:
  Log Kow used:  8.17  (KowWin est)
  Log Kaw used:  -8.501  (HenryWin est)
      Log Koa (KOAWIN v1.10 estimate):  16.671
      Log Koa (experimental database):  None

 Probability of Rapid Biodegradation (BIOWIN v4.10):
   Biowin1 (Linear Model)         :   1.2022
   Biowin2 (Non-Linear Model)     :   0.9941
 Expert Survey Biodegradation Results:
   Biowin3 (Ultimate Survey Model):   2.7518  (weeks       )
   Biowin4 (Primary Survey Model) :   3.5468  (days-weeks  )
 MITI Biodegradation Probability:
   Biowin5 (MITI Linear Model)    :   0.3030
   Biowin6 (MITI Non-Linear Model):   0.0906
 Anaerobic Biodegradation Probability:
   Biowin7 (Anaerobic Linear Model):  0.2710
 Ready Biodegradability Prediction:   NO

Hydrocarbon Biodegradation (BioHCwin v1.01):
    Structure incompatible with current estimation method!

 Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:
  Vapor pressure (liquid/subcooled):  3.11E-008 Pa (2.33E-010 mm Hg)
  Log Koa (Koawin est  ): 16.671
   Kp (particle/gas partition coef. (m3/ug)):
       Mackay model           :  96.6 
       Octanol/air (Koa) model:  1.15E+004 
   Fraction sorbed to airborne particulates (phi):
       Junge-Pankow model     :  1 
       Mackay model           :  1 
       Octanol/air (Koa) model:  1 

 Atmospheric Oxidation (25 deg C) [AopWin v1.92]:
   Hydroxyl Radicals Reaction:
      OVERALL OH Rate Constant = 383.5307 E-12 cm3/molecule-sec
      Half-Life =     0.028 Days (12-hr day; 1.5E6 OH/cm3)
      Half-Life =    20.080 Min
   Ozone Reaction:
      OVERALL Ozone Rate Constant =    86.000000 E-17 cm3/molecule-sec
      Half-Life =     0.013 Days (at 7E11 mol/cm3)
      Half-Life =     19.189 Min
   Reaction With Nitrate Radicals May Be Important!
   Fraction sorbed to airborne particulates (phi): 1 (Junge,Mackay)
    Note: the sorbed fraction may be resistant to atmospheric oxidation

 Soil Adsorption Coefficient (PCKOCWIN v1.66):
      Koc    :  2.5E+005
      Log Koc:  5.398 

 Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v1.67]:
    Rate constants can NOT be estimated for this structure!

 Bioaccumulation Estimates from Log Kow (BCFWIN v2.17):
   Log BCF from regression-based method = 1.000 (BCF = 10)
       log Kow used: 8.17 (estimated)

 Volatilization from Water:
    Henry LC:  7.72E-011 atm-m3/mole  (estimated by Bond SAR Method)
    Half-Life from Model River:  1.44E+007  hours   (6E+005 days)
    Half-Life from Model Lake : 1.571E+008  hours   (6.545E+006 days)

 Removal In Wastewater Treatment:
    Total removal:              94.02  percent
    Total biodegradation:        0.78  percent
    Total sludge adsorption:    93.24  percent
    Total to Air:                0.00  percent
      (using 10000 hr Bio P,A,S)

 Level III Fugacity Model:
           Mass Amount    Half-Life    Emissions
            (percent)        (hr)       (kg/hr)
   Air       0.00828         0.216        1000       
   Water     3.77            360          1000       
   Soil      28.2            720          1000       
   Sediment  68              3.24e+003    0          
     Persistence Time: 1.24e+003 hr

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