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21Interaction of the Negishi reagent Cp2ZrBunn 2 with 1,4-bis(tert-butyl)butadiyne, Russian Chemical Bulletin Formation of the five-membered zirconacyclocumulene Cp2Zr(??4-ButC4But) and the binuclear zirconocene butatrienyl complex Cp2(Bun)Zr(ButC4But)Zr(Bun)Cp2 in the reaction of the Negishi reagent with 1,4-di(tert-butyl)butadiyne, Russian Chemical Bulletin Novel solvent-controlled chemoselective palladium/copper(II) halide catalyzed oligomerization of tert-butyl acetylene, Research on Chemical Intermediates